Humboldt State University ® Department of Chemistry

Richard A. Paselk

 

Introductory Chemistry

Fall 2005

Exercise: Net IonicBalancing

© R. Paselk 2005
 
 

Worked Examples
 

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Balancing by Inspection - Net Ionic Equations

Write Balanced Net-Ionic Equations for the following Reactions in Aqueous Solution:

  1. Copper metal (Cu(s)) is immersed in an aqueous solution of silver nitrate (AgNO3). The solution turns light blue and a silver coating appears on the copper.

    1. First need to determine the species originally present and their formulae:
      Cu(s), Ag+(aq), NO3-(aq), Cu2+(aq), Ag(s).

    2. From the description, silver metal is made, so we can write the unbalanced reaction:
      Cu(s) + Ag+(aq) + NO3-(aq) Cu2+(aq) + NO3-(aq) + Ag(s)

    3. By inspection we see that the atoms are balanced, however charges are not. Balancing charge we get:
      Cu(s) + 2 Ag+(aq) + NO3-(aq) Cu2+(aq) + NO3-(aq) + 2 Ag(s)

    4. Finally, canceling species present on both sides gives:
      Cu(s) + 2 Ag+(aq) Cu2+(aq) + 2 Ag(s)

  2. Dilute solutions of antimony(III) chloride and sodium sulfide are mixed to give a precipitate.

    1. First need to determine species originally present and their formulae:
      Sb3+(aq), Cl-(aq), Na +(aq), S2-(aq).

    2. Since we know sodium chloride is soluble we can write the unbalanced reaction:
      Sb3+(aq) + 3 Cl-(aq) + Na +(aq)+ S2-(aq) 3 Cl-(aq) + Na +(aq) + Sb2S3 (s)

    3. By inspection we see that the atoms are not balanced, we need to add one antimony and two sulfides on the left:
      2 Sb3+(aq) + 3 Cl-(aq) + Na +(aq)+ 3 S2-(aq) 3 Cl-(aq) + Na +(aq) + Sb2S3 (s)

    4. Finally, canceling species present on both sides gives:
      2 Sb3+(aq) + 3 S2-(aq) Sb2S3 (s)

  3. Dilute solutions of silver nitrate and potassium iodide are combined and give a yellow precipitate.

    1. We know that potassium nitrate is soluble (there are no insoluble nitrates nor potassium salts), so the precipitate must be silver iodide:

    2. Ag+(aq) + NO3-(aq) + K +(aq) + I-(aq) K +(aq) + NO3-(aq)+ AgI(s)

    3. Ag+(aq) + I-(aq) AgI(s)

  4. Dilute solutions of aluminum chloride and sodium hydroxide are mixed, giving a gelatinous precipitate.

    1. We know that sodium chloride is soluble, so the precipitate must be aluminum hydroxide:

    2. Al3+(aq) + 3 Cl-(aq) + Na +(aq) + OH-(aq) 3 Cl-(aq) + Na +(aq) + Al(OH)3(s)

    3. Al3+(aq) + 3 OH-(aq) Al(OH)3(s)

  5. Dilute solutions of calcium chloride and sodium phosphate are combined to give a precipitate.

    1. We know that sodium chloride is soluble, so the precipitate must be calcium phosphate:

    2. Ca2+(aq) + 2 Cl-(aq) + 3 Na +(aq) + PO43-(aq) 2 Cl-(aq) + 3 Na+(aq) + Ca3(PO4)2

    3. 3 Ca2+(aq) + 2 PO43-(aq) Ca3(PO4)2

  6. Dilute solutions of nitric acid and sodium hydroxide are mixed, generating heat.

    1. This is an acid-base reaction, so water will be formed.

    2. H+(aq) + NO3-(aq) + Na+(aq) + OH-(aq) NO3-(aq) + Na+(aq) + H2O(l)

    3. H+(aq) + OH-(aq) H2O(l)

  7. Dilute solutions of sulfuric acid and sodium hydroxide are mixed, generating heat.

    1. This is an acid-base reaction, so water will be formed. Bisulfate is a weak acid.

    2. H+(aq) + HSO4-(aq) + Na+(aq) + OH-(aq) SO42-(aq) + Na+(aq) + H2O(l)

    3. H+(aq) + HSO4-(aq) + 2 OH-(aq) SO42-(aq) + 2 H2O(l)

  8. A dilute solution of hydrochloric acid is poured over limestone (calcium carbonate) and a non-flammable, odorless gas is released as the rock dissolves.

    1. From the description, the most likely gas is carbon dioxide.

    2. H+(aq) + Cl-(aq) + CaCO3(s) Ca2+(aq) + Cl-(aq) + CO2(g) + H2O(l)

    3. 2 H+(aq) + CaCO3(s) Ca2+(aq) + CO2(g) + H2O(l)

  9. Dilute solutions of lead(II) nitrate and sodium chloride are combined and give a white precipitate.

      1. We know that sodium nitrate is soluble (there are no insoluble nitrates nor sodium salts), so the precipitate must be lead chloride:

      2. Pb2+(aq) + 2 NO3-(aq) + Na+(aq) + Cl-(aq) Na+(aq) + 2 NO3-(aq + PbCl2 (s)

      3. Pb2+(aq) + 2 Cl-(aq) PbCl2 (s)

  10. Dilute solutions of barium chloride and sodium sulfate are combined to give a white insoluble precipitate.

    1. We know that sodium chloride is soluble, so the precipitate must be barium sulfate:

    2. Ba2+(aq) + 2 Cl-(aq) + 2 Na +(aq) + SO42-(aq) 2 Cl-(aq) + 2 Na+(aq) + BaSO4

    3. Ba2+(aq) + SO42-(aq) BaSO4


© R A Paselk

Last modified 23 June 2006