Humboldt State University ® Department of Chemistry

Richard A. Paselk

Chem 109

General Chemistry

Spring 2009

Lecture Notes:: 26 January

© R. Paselk 2002
 
     
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Exponential or scientific notation:

It is often convenient to express numbers in exponential or scientific notation to indicate significant figures, and to just avoid writing the huge numbers of zeros we often run into in the natural world. [covered in problem session]

SI Units (metric system)

SI Units: The metric system originated around the French Revolution as a rational system of measurements to rescue France from the chaos of pre-revolutionaary measurements and thus prevent tax collectors from cheating.

Wanted to base system on "natural" universal standards. Thus for length they chose the size of the Earth: specifically the meter was defined as one ten-millionth (10-7) of the Earth's meridian (line from the S to the N pole) through Paris. For mass the Kilogram was defined as the mass of a cube of water 0.1 meter on a side. Of course these are not convenient, so standards were quickly created: the meter became the distance between two lines on a platinum-iridium bar stored in a vault in Paris, while the kilogram became a cylindrical mass of platinum-iridium stored in the same vault.

Today the various units are defined by international agreement to give the SI (Systéme International) units:

Prefixes: Note Table 1.2 in your text (p 9). You should know (memorize) and be able to interconvert the prefixes in the table below:

Prefix Symbol Magnitude
tera-
T
1012
giga-
G
109
mega-

M

 106
kilo- k 103
base   100
deci- d 10-1
centi- c 10-2
milli- m 10-3
micro-

mu (or mc)

10-6
nano- n 10-9
pico- p 10-12
fempto- f 10-15

Memorize: 1 mL = 1 cm3; 1 inch = 2.54 cm (defined); 1 liter is about 1 quart; density of water = 1 g/mL; 0° C = 32 °F, 100°C = 212 °F, -40 °C = -40 °F.

Temperature

Look in your text for conversions between °C and °F and example problems

Density

Density is defined as the mass of a given volume of a substance: Density = mass/volume. Note that this weeks laboratory exercise give practice in Density, significant figures etc.

Let's try some density problems. First note that the units of density are g/cm3 or g.cm-3.

Known: Density = mass/volume, generally expressed as g/mL = g/cm3

Solve: (35.987 g) / (20.0 mL) = 1.79935 g/mL

note that the units are those of density so we are confident we set it up correctly.

How about sig figs? Use multiplication/division rules, so count: 3 for 20.0 and 5 for 35.987, therefore should have three sig figs:

1.79935 g/mL = 1.80 g/mL

Extra Example: Using a jewelers balance a student found that a coin weighed 2.34 carats in air. By weighing it again submerged in water she found it had a volume of 0.034 mL. What is its density? (1 carat = 200 mg, defined)*

Known: 1 carat = 200 mg (defined), density is g/mL

Solve: (2.34 carats)(200 mg/carat)(1 g/1,000 mg) / 0.034 mL = 13.764706 g/mL

How about sig figs? Both conversion factors are defined, so exact. Two measurements: 2.34 and 0.034 = 3.4 x 10-2. Thus the answer will have only two sig figs since using counting rule - least number of sig figs.

13.764706 g/mL = 14 g/mL


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Last modified 26 January 2009